Why do citric acid and baking soda only react with water?

Introduction: Citric acid and baking soda

Citric acid and baking soda are two common household substances that are often used in cooking, cleaning, and various other applications. When mixed together, they undergo a chemical reaction that produces carbon dioxide gas, which can be useful for a variety of purposes such as leavening baked goods or creating fizzy drinks. However, this reaction only occurs under certain conditions, and understanding the science behind it can help us better utilize these substances in our everyday lives.

What is citric acid?

Citric acid is a weak organic acid that is naturally found in many fruits and vegetables, particularly citrus fruits such as lemons and limes. It is commonly used as a food preservative, flavor enhancer, and cleaning agent due to its acidic properties. Citric acid is also used in the production of cosmetics, medicines, and other products.

What is baking soda?

Baking soda, also known as sodium bicarbonate, is a white crystalline powder that is commonly used as a leavening agent in baking. When baking soda is combined with an acid (such as citric acid), it undergoes a chemical reaction that produces carbon dioxide gas, which causes dough to rise. Baking soda is also used in cleaning and deodorizing products due to its ability to neutralize odors and dissolve grease and dirt.

Chemical reaction basics

Before we can understand why citric acid and baking soda react, we need to understand some basic principles of chemical reactions. Chemical reactions involve the breaking and forming of chemical bonds between atoms and molecules. In order for a reaction to occur, the reactants (the substances being combined) must come into contact with each other and have enough energy to overcome the activation energy barrier, which is the energy required to start the reaction.

Why do citric acid and baking soda react?

Citric acid and baking soda react because they are both acidic substances that can donate and accept protons (H+ ions) in chemical reactions. Baking soda is a base (alkaline) substance that contains bicarbonate ions (HCO3-), which can accept a proton from an acid. Citric acid is an acid that contains hydrogen ions (H+), which can donate a proton to a base. When citric acid and baking soda are combined, they undergo a chemical reaction in which the bicarbonate ion from the baking soda reacts with the hydrogen ion from the citric acid to form carbon dioxide gas (CO2).

What happens when they react?

When citric acid and baking soda react, they produce carbon dioxide gas, which can be observed as bubbles or fizzing. The chemical equation for the reaction is:

citric acid + baking soda -> carbon dioxide + water + sodium citrate

This reaction is exothermic, meaning it releases energy in the form of heat. The amount of carbon dioxide produced depends on the amount of citric acid and baking soda used, as well as the temperature and other conditions.

Why does it only happen with water?

The reaction between citric acid and baking soda only occurs with water because water is required for the reaction to proceed. Water is needed to dissolve the citric acid and baking soda, which allows the bicarbonate ions and hydrogen ions to come into contact and react. In addition, water helps to regulate the pH levels and acidity of the reaction, which is crucial for the reaction to occur.

pH levels and acidity

The pH level of a substance is a measure of its acidity or alkalinity, with a pH of 7 being neutral, lower pH values indicating acidity, and higher pH values indicating alkalinity. The reaction between citric acid and baking soda requires a certain level of acidity in order to occur. If the pH is too high, the reaction will not occur, and if the pH is too low, the reaction will be too vigorous and may produce unwanted side effects.

Other factors that affect the reaction

There are several other factors that can affect the reaction between citric acid and baking soda, including temperature, pressure, and the amount and concentration of the reactants. Higher temperatures can speed up the reaction, while higher pressures can increase the amount of carbon dioxide produced. Increasing the amount of citric acid or baking soda used can also affect the reaction.

Applications of citric acid and baking soda

Citric acid and baking soda have a wide range of applications, both individually and together. Citric acid is commonly used as a food preservative, flavor enhancer, and cleaning agent, while baking soda is used as a leavening agent in baking and as a cleaning and deodorizing agent. When combined, they can be used to create fizzy drinks, leaven baked goods, and clean and deodorize surfaces.

Conclusion: Citric acid and baking soda’s unique reaction

The reaction between citric acid and baking soda is a unique and useful phenomenon that can be utilized in a variety of applications. Understanding the science behind this reaction can help us better utilize these substances in our everyday lives, and may even inspire new applications and innovations in the future.

References and further reading

  1. "Citric Acid – an overview." ScienceDirect. https://www.sciencedirect.com/topics/chemistry/citric-acid
  2. "Sodium Bicarbonate – an overview." ScienceDirect. https://www.sciencedirect.com/topics/chemistry/sodium-bicarbonate
  3. "Chemical Reactions." Khan Academy. https://www.khanacademy.org/science/chemistry/chemical-reactions-stoichiome/introduction-to-chemical-reactions/a/chemical-reactions-stoichiometry
  4. "Acid-Base Reactions." Chemguide. https://www.chemguide.co.uk/physical/acidbaseeqia/introduction.html
  5. "pH and pKa." Chemguide. https://www.chemguide.co.uk/physical/acidbaseeqia/ph.html
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Elise DeVoe

Elise is a seasoned food writer with seven years of experience. Her culinary journey began as Managing Editor at the College of Charleston for Spoon University, the ultimate resource for college foodies. After graduating, she launched her blog, Cookin’ with Booze, which has now transformed into captivating short-form videos on TikTok and Instagram, offering insider tips for savoring Charleston’s local cuisine.

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